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Introduction


Background
¡¡Chlorodifluoromethane (R-22 or HCFC-22) has been used as a refrigerant in various refrigeration, indus-trial cooling, air conditioning, and heating applica-tions for over five decades. The low ozone depletion potential of R-22 compared to CFC- 11 (chloro-fluorocarbon 1 l) and CFC-12 and its excellent refrigerant properties have helped facilitate the transition away from CFCs. However, R-22 will be phased out in the first quarter of the 21 st century. In preparation for this phaseout, DuPont offers Suva® 407C and Suva® 410A, environmentally acceptable alternatives to R-22.

Suva® 407C and Suva® 410A Refrigerant Descriptions
¡¡Suva® 407C is a non-ozone-depleting blend of three hydrofiuorocarbon (HFC) refrigerants. It exhibits performance characteristics similar to R-22. Suva®410A is a non-ozone-depleting blend of two HFC refrigerants. It exhibits higher pressures and refrigera-tion capacity than R-22.

The compositions of Suva® 407C and Suva® 410A are as follows:

¡¡Because Suva® 407C and Suva® 410A are mixtures ofHFCs, they have zero ozone depletion potential.
¡¡Table 1 lists the chemical names and formulae of the components that make up Suva® 407C and Suva®410A.

Uses
¡¡Suva® 407C refrigerant performs similarly to HCFC-22 under evaporator temperatures ranging from -7 to 10~C (20 to 50~F). It is designed for use in new equipment and as a service refrigerant for existing HCFC-22 air conditioner and heat pump equipment.

¡¡Suva® 410A is intended for use in new air condition-ing applications that have traditionally been serviced by HCFC-22. Many other applications are also possible such as medium and low temperature refrig-eration. Due to the significantly higher pressures that Suva® 410A exhibits compared to HCFC-22, a typical compressor designed for HCFC-22 cannot be used with Suva® 410A.

¡¡Table 2 shows theoretical performance of Suva®407C, Suva® 410A, and HCFC-22. Suva® 407C exhibits similar performance to HCFC-22, while Suva® 410A gives significantly higher pressures and refrigeration capacity.

Physical Properties
¡¡General physical properties for Suva® 407C and Suva® 410A are shown in Table 3. The pressure-enthalpy diagrams for Suva® 407C are shown in Figures 1 and Figures 2.

¡¡Additional physical property data may be found in other DuPont publications. Bulletin ART-26 contains viscosity, thermal conductivity, and heat capacity for the liquid and vapor phases of Suva®407C. Bulletin ART-31 contains viscosity, thermal conductivity, and heat capacity for the liquid and vapor phases of Suva® 410A. Thermodynamic properties booklets are also available for Suva® 407C and Suva® 410A in both English and metric units.

Chemical/Thermal Stability
Stability with Metals
¡¡Stability tests for refrigerants with metals are typically performed in the presence of refrigeration lubricants. This test is run in sealed glass tubes at temperatures much higher than those encountered in refrigeration and air conditioning systems and is therefore referred to as an accelerated aging test. Results of sealed tube stability tests for HCFC-22/mineral oil and alkyl- benzene lubricants have shown long-term stability in contact with copper, steel, and aluminum. And the tact that HCFC-22/mineral oil and alkylbenzene systems have been performing in the field in air conditioner and refrigeration systems for the last 50 years verifies the results from these stability tests. Polyol ester lubricants (POEs) are among the pro-posed lubricants for use with Suva® 407C and Suva®410A. Therefore, stability tests of these refrigerants with POEs and metals were performed.

¡¡The test method followed was generally the same as ASHRAE 97 with several minor modifications. A 3-mL volume of refrigerant/lubricant solution was heated in the presence of copper, steel, and aluminum coupons in an oven for 14 days at 175~C (347~F) or 200~C (392~F) for 14 days. Both the neat refrigerant and a mixture of lubricant and refrigerant (50/50 volume ratio) were tested. Stability and visual ratings were obtained on both the liquid solutions and the metal coupons after the designated exposure time. The stability ratings range from 0 to 5, with 0 being the best and 5 being the worst. Visual ratings indicate how the metal or refrigerant or lubricant/refrigerant solution appeared to a visual inspection. A rating of "0" indicates no perceptible change in appearance. Any perceptible change of color, clarity, or surface finish changes the rating to "1 ." Mixtures of CFC refrigerants and conventional mineral oils generally get a rating of "3," which is the limit of acceptability. The new refrigerants and lubricants must outperform those being replaced in order to be considered acceptable.

¡¡After the visual ratings were obtained, sample tubes were opened, and the lubricant and refrigerant were analyzed. The lubricant was typically checked for halide content and breakdown products, while the refrigerant was examined for the presence of decom-position products. Table 4 summarizes the data from these sealed tube stability tests for Suva® 407C and Suva® 410A and various commercial POE lubricants. Stability and visual ratings are listed for the neat refrigerant, the lubricant/refrigerant solution, and the three metals that were present in the lubricant/ refrigerant solutions. Samples were analyzed for decomposition products in most cases. Typical level measurements for decomposition products, if they are detected, are in the low parts per million (ppm) range.
The results obtained from these sealed tube stability tests for Suva® 407C/POEs and Suva® 410A/POEs indicate acceptable chemical stability in the presence of common metals used in refrigeration and air conditioner systems.

Note: Lubricant/refrigerant combinations shown throughout this report are for purposes of comparing and illustrating the stability and compatibility of different lubricants with Suva® refrigerants. No recommendation is made or implied. Contact your equipment manufacturer for the recommended lubricant for use with Suva® refrigerants.

Thermal Decomposition
¡¡Like HCFC-22, Suva® 407C and Suva® 410A refriger- ants will decompose when exposed to high tempera- ture or flame sources. Decomposition may produce toxic and irritating compounds, such as hydrogen fluoride. The decomposition products released will irritate the nose and throat. Therefore, it is important to prevent exposure to decomposition products by following DuPont Material Safety Data Sheet (MSDS) recommendations for handling.

Compatibility Concerns If HCFC-22and Suva® Refrigerants Are Mixed
¡¡HCFC-22 and Suva® refrigerants are chemically compatible with each other. This means they do NOT react with each other and form other compounds. However, when these refrigerants are mixed by accident or deliberately, they will form mixtures that can be difficult to separate. Mixtures of HCFC-22 and Suva® refrigerants cannot be separated in on-site recycle machines or in typical facilities of an off-site reclaimer. These mixtures will have to be disposed of by incineration.

¡¡Also, mixtures of HCFC-22 and Suva® 407C or Suva®410A refrigerants will have performance properties different than either refrigerant alone. Therefore, we do not recommend mixing HCFC-22 and Suva®refrigerants in any system.

Materials Compatibility
¡¡Because Suva® refrigerants will be used in many different applications, it is important to review materials of construction for compatibility when designing new equipment, retrofitting existing equip-ment, or preparing storage and handling facilities. The following compatibility data is for Suva® 407C and Suva® 410A with some elastomers and plastics commonly found in air conditioning and refrigeration systems.

Compatibility with Elastomers
¡¡Compatibility results are listed in Table 5 for HCFC-22 neat, Suva® 407C neat, and Suva® 407C/ polyol ester lubricant mixture, in the presence of elastomers. Table 6 presents similar data for Suva® 410A. It should be recognized that these data reflect compatibility in sealed tube tests, and that refrigerant compatibility in real systems can be influenced by the actual operating conditions, the nature of the poly- mers used, compounding formulations of the poly- mers, and the curing or vulcanization processes used to create the polymer. Polymers should always be tested under actual operating conditions before reaching final conclusions about their suitability.

The ratings shown in Tables 5 and Table 6 are based on. samples of each elastomer subjected to aging in a sealed tube in the presence of the refrigerant and lubricant. For the neat refrigerant (both HCFC-22 and Suva® refrigerant), the aging occurred for two weeks at room temperature. For the Suva® refrigerant/polyol ester lubricant mixture, aging occurred for two weeks at 100'C (212'F). Physical properties of the sample elastomers were measured before and after aging.

Compatibility with Plastics
¡¡Compatibility results are listed in Table 7 for R-22 neat, Suva® 407C neat, and Suva® 407C/polyol ester lubricant mixture, in the presence of plastics. Table 8 presents similar data for Suva® 410A. It should be recognized that these data reflect compat-ibility in sealed tube tests, and that refrigerant com-patibility in real systems can be influenced by the actual operating conditions, the nature of the poly-mers used, and the compounding formulations of the polymers. Polymers should always be tested under actual operating conditions before reaching final conclusions about their suitability.

¡¡The ratings shown in Table 7 and Table 8 are based on samples of each plastic subjected to aging in a sealed tube in the presence of the refrigerant and lubricant. For the neat refrigerant (both HCFC-22 and Suva®refrigerant), the aging occurred for two weeks at room temperature. For the Suva® refrigerantJpolyol ester lubricant mixture, aging occurred for two weeks at 100'C (212'F). Physical properties of the sample plastics were measured before and after aging.

¡¡Refrigerant comes in contact with the motor windings in hermetic and semi-hermetic compressors. As a result, the motor materials must be compatible with the refrigerant and lubricant used in the system. Equipment manufacturers have tested the compatibil-ity of their motor materials with Suva® refrigerants£¬and polyol ester lubricants. Be sure to check with the manufacturer of your equipment before using Suva®refrigerant in any hermetic or semi-hermetic compressor.

Compatibility with Desiccants
¡¡In refrigeration systems, keeping the refrigerant and lubricant free of moisture is very important. Dryers filled with moisture-absorbing desiccant are typically used to prevent moisture accumulation. The XH-6 desiccant produced by UOP is typically used for R22. While this desiccant, as well as UOP's XH-9, is compatible with Suva® 407C and Suva® 410A, both desiccants will absorb R32. The XH-11 desiccant from UOP is compatible with Suva® 407C and Suva®410A and will exclude R32. Sporlan~ and Alco offer solid core driers that are compatible with Suva® 407C and Suva® 410A.

Refrigeration Lubricants
¡¡Most compressors require a lubricant to protect internal moving parts. The compressor manufacturer usually recommends the type of lubricant and proper viscosity that should be used to ensure acceptable operation and equipment durability. Recommenda-tions are based on several criteria, which can include:
+ lubricity
+ lubricant/refrigerant solubility
+ lubricant/refrigerant miscibility
+ compatibility with materials of construction
+ thermal stability and compatibility with other lubricants
¡¡It is important to follow the manufacturer's recom-mendations for lubricants to be used with their equipment.
¡¡Lubricant return to the compressors is very important as well. One factor that affects this is the liquid-phase lubricant/refrigerant miscibility, particularly at evaporator temperatures. Miscibility is the ability of two liquids to mix and form a single liquid phase--similar to water and alcohol. Ideally, the lubricant/refrigerant pair have sufficient miscibility or mutual solubility to allow the lubricant to flow with the liquid refrigerant and return to the compressor. Even if the lubricant/refrigerant pair are not miscible (two liquid phases form) in the evaporator, they may still have some degree of solubility. Solubility of refrigerant in lubricant lowers lubricant viscosity, which helps it flow through the evaporator and return to the com-pressor. This is why many refrigeration systems can operate properly, even though the lubricant and refrigerant are immiscible (yet partially soluble) at evaporation temperatures. Other factors, such as refrigerant vapor velocity and system geometry, play key roles in lubricant return. Overall, it is important to note that lubricant/refrigerant miscibility is helpful, but not necessarily essential for proper system operation.
¡¡Note that HCFC-22/mineral oil and HCFC-22/alkylbenzene liquid phase miscibility are listed for reference. In general, HCFC-22 and mineral oil are miscible over most of the expected ranges of operat-ing conditions for normal air conditioning and high to medium temperature operation. HCFC-22 and alkylbenzene are miscible over a much wider range of temperatures. Miscibility is generally believed to aid lubricant return to the compressor. Therefore, it may be desirable in a retrofit of an existing system of this type to use a miscible lubricant with Suva® HFC refrigerants. In general, Suva® HFC refrigerants such as Suva® 407C and Suva® 410A are miscible with polyol ester lubricant and immiscible with alkylbenzene and mineral oil lubricant. Another important point is that residual mineral oil or alkylbenzene left in a refrigeration system after a retrofit to any HFC refrigerant is performed decreases the lubricant/refrigerant miscibility. This is one of the reasons why three oil changes are generally recom-mended when a system is being converted or retrofit to use HFC refrigerants and POE lubricants.

¡¡Table 9 lists the liquid phase miscibility of Suva®407C and Suva® 410A refrigerants with multiple lubricants. The miscibility is determined by several factors: the relative amounts of refrigerant and
lubricant present, the temperature, the chemical makeup of the lubricant and of the refrigerant, and the viscosity of the lubricant. The table shows the tem-perature range over which several different composi-tions of refrigerant and lubricants are fully miscible.

¡¡Compressor and equipment manufacturers are testing and recommending lubricants for use in their equip-ment with Suva® 407C and Suva® 410A refrigerants. There will be continuing research and development of new lubricants by the equipment manufacturers in years to come. Therefore, we strongly recommend that you review your system lubricant needs with the equipment manufacturers before any unit installation or retrofit to Suva® 407C or Suva®410A refrigerant.

Safety
Inhalation Toxicity
¡¡Suva® 407C and Suva® 410A refrigerants pose no acute or chronic hazard when handled in accordance with DuPont recommendations and when exposures are maintained at or below recommended exposure limits, such as the DuPont Acceptable Exposure Limit (AEL) of 1000 ppm. An AEL is an airborne exposure limit established by DuPont that specifies time-weighted average (TWA) airborne concentrations,usually 8 hr, to which nearly all workers may be repeatedly exposed without adverse effects. In practice, short-term exposures should not exceed three times the established exposure limit for more than a total of 30 min during a workday.

¡¡The exposure limits of 1000 ppm for Suva® 407C and Suva® 410A refrigerants are the same level as the Threshold Limit Value (TLV) established for HCFC-22. However, like HCFC-22, inhalation exposure above the recommended exposure limit to the vapors of Suva® 407C or Suva® 410A refrigerants may cause human health effects that can include temporary nervous system depression with anesthetic effects such as dizziness, headache, confusion, loss of coordination and even loss of consciousness. If you experience any of the above initial symptoms, move to fresh air and seek medical attention as a precaution. Gross overexposure may be fatal.

Cardiac Sensitization
¡¡An effect that occurs with most hydrocarbons and halocarbons at high concentrations is that the human heart can become sensitized to adrenalin (cardiac sensitization.) This can lead to cardiac irregularities such as irregular pulse, palpitations, inadequate circulation, and even cardiac arrest. The likelihood of these cardiac problems increases if you are under physical or emotional stress (due to the potential for increased amounts of adrenalin in your system). Suva® 407C and Suva® 410A refrigerants can cause cardiac sensitization at inhalation levels well above the recommended exposure limit, but the effect level varies from person to person. If you experience any of the above symptoms of cardiac sensitization, move to fresh air and seek medical attention as a precaution. Gross overexposure may be fatal.

¡¡As part of treatment for cardiac sensitization, DO NOT treat the patient with catecholamines such as adrenaline, because these drugs could increase the risk of cardiac problems.

Skin and Eye Contact
¡¡Always wear protective clothing when there is a risk of exposure to liquid Suva® 407C or Suva® 410A refrigerants. In liquid form, Suva® 407C and Suva®410A refrigerants can cause frostbite. Where splash-ing of liquid refrigerant is possible, always wear eye protection. If skin or eyes are splashed with liquid Suva® 407C or Suva® 410A refrigerant, flush area with lukewarm water (do not use hot water). If frostbite has occurred, call a physician. If eyes are splashed, immediately flush with plenty of water for at least 15 min. Call a physician.

Spills or Leaks
¡¡It' a large release of vapor occurs, such as from a large spill or leak, the vapors may concentrate near the floor or in low spots and displace the oxygen avail-able for breathing. This could cause suffocation. When a large spill or leak occurs, always wear appropriate respiratory and other personal protective equipment. Evacuate everyone from the area until it has been ventilated. Use blowers or fans to circulate the air at floor level. Do not reenter the affected area unless you are equipped with a self-contained breath-ing apparatus.

Nonflammability
¡¡Nonflammability is an essential requirement for refrigerants used in the air conditioning industry. Although HFC-32 is a flammable compound, Suva®407C and Suva® 410A refrigerants are formulated such that they remain nonflammable during shipping, handling, storage, use, and if they leak from a unit. Suva® 407C and Suva® 410A refrigerants are classi-fied as A 1/Al refrigerants by ASHRAE. Also, Suva®407C and Suva® 410A refrigerants have been con-firmed as practically nonflammable (the same as R-22) by Underwriters Laboratories, Inc. (USA) and both are on their list of recognized refrigerants.

Combustibility of Suva® 407C and Suva® 410A
¡¡Both Suva® 407C and Suva® 410A have been confirmed as nonflammable at atmospheric pressure at temperatures up to practical limits accepted by Underwriters' Laboratories. However, tests have shown that some hydrogen-containing fluorocarbons which are not flammable at atmospheric pressure can become combustible at elevated pressures in the presence of large quantities of ail'. HCFC-22 and HFC-134a have this characteristic.

¡¡Suva® 407C and Suva® 410A have not been tested for combustibility at elevated pressure in the presence of large quantities of air, but Suva® 407C contains HFC-134a and both Suva® 407C and Suva® 410A contain a flammable component, HFC-32. The presence of these chemicals suggests that Suva® 407C or Suva®410A are likely to have the tendency for elevated-pressure combustibility described above. Therefore, Suva® 407C or Suva® 410A should not be mixed with air for leak testing. In general, neither product should be used or allowed to be present with high concen-trations of air above atmospheric pressure.

Air Monitors and Leak Detection
¡¡Service personnel have used leak detection equipment for years when servicing equipment. Leak detectors exist not only for pinpointing specific leaks, but also for monitoring an entire room on a continual basis for the absence of oxygen or presence of refrigerant. There are several reasons for leak pinpointing or area monitoring, including: conservation of refrigerants,protection of valuable equipment, reduction of fugitive emissions, and protection of employees.

¡¡Prior to the purchase of a detector or monitor, make sure you consider your requirements or criteria for the monitor such as sensitivity, detection limits, and selectivity.

Types of Detectors
¡¡Using selectivity as a criteria, leak detectors can be placed into one of three categories: nonselective, halogen-selective, or compound-specific. In general, as the specificity of the monitor increases, so does the complexity and cost. Other methods used to find leaks are to add fluorescent additives to the system or coat the suspect area with a soapy-water solution and look for soap bubbles.

¡¡A detailed discussion of leak detection is given in bulletin ARTD-27A.

Nonselective Detectors
¡¡Nonselective detectors are those that will detect any type of emission or vapor present, regardless of its chemical composition. These detectors are typically quite simple to use, very durable, inexpensive, and usually portable. However, their inability to be calibrated, long-term drift, lack of selectivity, and lack of sensitivity limit their use for area monitoring.

Halogen-Selective Detectors
¡¡Halogen-selective detectors use a specialized sensor that allows the monitor to detect compounds contain-ing fluorine, chlorine, bromine, and iodine without interference from other species. The major advantage of such a detector is a reduction in the number of "nuisance alarms"--false alarms caused by the pres-ence of some compound in the area other than the target compound.
¡¡These detectors are typically easy to use, feature higher sensitivity than the nonselective detectors (detection limits are typically <5 ppm when used as an area monitor and <0.05 oz/yr when used as a leak pinpointeD, and are very durable. In addition, due to the partial specificity of the detector, these instru- ments can be calibrated easily.

Compound-Specific Detectors
¡¡The most complex detectors, which are also the most expensive, are compound-specific detectors. These units are typically capable of detecting the presence of a single species without interference from other compounds.

Fluorescent Additives
¡¡Fluorescent additives have been used in refrigeration systems for several years. These additives, invisible under ordinary lighting, but visible under ultraviolet (UV) light, are used to pinpoint leaks in systems. The additives are typically placed into the refrigeration lubricant when the system is serviced. Leaks are detected by using a UV light to search for additive that has escaped from the system. The color of the additive when subjected to UV light is normally a bright green or yellow and is easily seen.

¡¡As a leak pinpointer, fluorescent additives work very well, because large areas can be rapidly checked by a single individual. And, the recent introduction of battery-powered UV lights has made this task even simpler. Leak rates of less than 0.25 oz/yr can be found with the additives. The only drawback to the use of additives is that some areas may be visually unobservable due to cramped spaces.

¡¡One cautionary note concerning the use of fluorescent additives: the compatibility of the specific additive with the lubricant and refrigerant should be tested prior to use. For detailed information about which lubricants and refrigerants have been tested with which additives, contact the fluorescent additive manufacturers.

Storage and Handling
Shipping Containers in the U.S.
¡¡Suva® 407C and Suva® 410A refrigerant blends are liquefied gases. According to the U.S. Department of Transportation (DOT), a nonflammable compressed gas is defined as a nonflammable material having an absolute pressure greater than 40 psi at 21'C (70'F) and/or an absolute pressure greater than 104 psi at 54'C (130'F).

¡¡The appropriate DOT designations for both Suva®407C and Suva® 410A are as follows: Proper shipping name for Suva® 410A: Liquefied Gas, N.O.S. (contains difluoromethane and pentafluoroethane)

¡¡Proper shipping name for Suva® 407C: Liquefied Gas, N.O.S. (contains difiuoromethane, penta-fluoroethane and 1,1,1,2-tetrafluoroethane)

¡¡Hazard class: Nonflammable Gas UN/NA no.: UN3163

¡¡Three different types of containers can be used to ship Suva® 407C; their water capacity, dimensions, and DOT specifications are provided in Table 10.

¡¡The 30 lb cylinder, known as a Dispose A Can~(DAC), fits into a box that measures 10 x 10 x 17 in. "Dispose A Can" is the DuPont registered trade name for this type of single-use container. The DAC valve will be standard for Suva® 407C.

¡¡Three different types of containers can be used to ship Suva® 410A; their water capacity, dimensions, and DOT specifications are provided in Table 11.

Bulk Storage Systems
¡¡DuPont can supply storage systems to its Suva® 407C and Suva® 410A customers. The systems are prefabri-cated, tested, and ready to install on-site. The units are designed to optimize economy, efficiency, and safety in the storage and dispensing of Suva® 407C or Suva®410A. The delivered systems include all components, such as storage tanks, pumps, piping, valves, motors, and gauges, as an integrated unit. All systems are equipped with the DuPont Fluorochemical Emission Elimination Delivery (FEED) system to preventemissions during deliveries and with dual pumps to provide an installed spare. The units are skid-mounted and require only placement on a concrete pad and connection to electrical and process systems.

¡¡A typical bulk storage system is shown in Figure 3.

¡¡Your DuPont Marketing Representative can arrange for guidance on site selection, purchase, installation, start-up, and maintenance.

Converting Bulk Storage Tanks from HCFC-22 to Suva® 407C or Suva® 410A
¡¡Before switching from HCFC-22 to Suva® 407C or 410A, the existing storage equipment must be checked to verify that it is adequate. Storage tanks built to the specifications of the American Society of Mechanical Engineers (ASME) Pressure Vessel Code are required to have a metal nameplate indicating each tank's maximum allowable working pressure (MAWP). The rating must be 285 psig (2065 kPa abs) or higher for Suva® 407C service. The rating must be 400 psig (2857 kPa abs) or higher for Suva® 410A service. The set pressure and capacity of the relief devices on the top of the tanks must also be verified and changed, if necessary.

Note: Most bulk storage tanks currently in service for HCFC-22 are NOT suitable for Suva® 407C or Suva®410A due to an inadequate pressure rating.

¡¡We recommend that storage tanks be completely emptied of all HCFC-22 liquid and vapor before introducing Suva® 407C or Suva® 410A. In general, converting a storage tank from HCFC-22 requires:
1. Removing HCFC-22 from the storage tank, lines and equipment.
2. Evacuating the storage tank to 25 in of mercury vacuum (16.7 kPa abs) and ¡¡purging with com- pressed dry nitrogen.
3. Making necessary repairs to the tank after initial evacuation and purging.
4. Repeating step 2 until HCFC-22 and moisture analyses are within acceptable ¡¡limits.
5. Refilling system with the appropriate refrigerant (Suva® 407C or Suva® 410A).

¡¡The preceding is a simplified outline of what is actually a lengthy procedure. Your DuPont Marketing Representative can assist in obtaining the equipment, instrumentation, and technical assistance to safely and effectively make the conversion.

Material Compatibility Concerns
¡¡Most metal components suitable for use with HCFC-22 are also compatible with Suva® 407C and Suva®410A, including standard types of carbon steel, aluminum, and copper. Some elastomeric or non-metallic components suitable for HCFC-22 may not be adequate. Therefore, all elastomeric or nonmetallic components throughout the system must be identified and their compatibility with Suva® 407C or Suva®410A verified. See Material Compatibility section. For complete reliability, any component that cannot be properly identified should be replaced.

¡¡In a fluorocarbon storage system, elastomers are most commonly found in:
+ Packing and seats of manual valves
+ Pressure-relief device seats
+ Flange and manway gaskets
+ Mechanical pump seals
+ Wet-end pump gaskets and O-rings
+ Filter O-rings
+ Sight-flow indicator gaskets
+ Back-pressure regulator diaphragms and O-rings

Handling Precautions for Suva® 407C and Suva® 410A Shipping Containers
¡¡The following rules for handling Suva® 407C and Suva® 410A containers are strongly recommended:
+ Use personal protective equipment, such as side shield glasses, gloves, and safety shoes when handling containers.
+ Avoid skin contact with liquid Suva® 407C or Suva® 410A, because it may cause frostbite.
+ Never heat a container to a temperature higher than 52'C (125'F).
+ Never apply direct flame or live steam to a con- tainer or valve.
+ Never refill disposable cylinders with anything. The shipment of refilled disposable cylinders is prohib-ited by DOT regulations.
+ Never refill returnable cylinders without DuPont consent. DOT regulations forbid transportation of returnable cylinders refilled without DuPont authorization.
+ Never use a lifting magnet or sling (rope or chain) when handling containers. A crane may be used when a safe cradle or platform is used to hold the container.
+ Never use container for rollers, supports, or any purpose other than to carry Suva® 407C or Suva® 410A.
+ Protect containers from any object that will result in cut or other abrasion in the surface of the metal.
+ Never tamper with the safety devices in the valves or containers.
+ Never attempt to repair or alter containers or valves.
+ Never force connections that do not fit. Make sure the threads on the regulators or other auxiliary equipment are the same as those on the container valve outlet.
+ Keep valves tightly closed, and valve caps and hoods in place when the containers are not in use.
+ Store containers under a roof to protect them from weather extremes.
+ Use a vapor recovery system to collect Suva® 407C and Suva® 410A vapors from lines after unloading a container.
¡¡Table 12

Recovery, Reclamation, Recycle, and Disposal
Recovery
¡¡Recovery refers to the removal of' Suva® 407C or Suva® 410A from equipment and collection in anappropriate external container. As defined by the Air Conditioning and Refrigeration Institute (ARI), a U.S. organization, recovery does not involve processing or analytical testing. Suva® 407C or Suva® 410A may be recovered from refrigeration equipment using perma-nent on-site equipment or one of the portable recovery devices now on the market. The portable devices contain a small compressor and an air-cooled con-denser and may be used for vapor or liquid recovery. At the end of the recovery cycle, the system is evacu-ated to remove vapors. In the United States, the Environmental Protection Agency (EPA) sets stan-dards for recovery equipment. Before purchasing a specific recovery unit, check with the manufacturer to be sure that it can be used to recover Suva® 407C or Suva® 410A.

Reclamation
¡¡Reclamation refers to the reprocessing of used Suva®407C and Suva® 410A to new product specifications.Quality of reclaimed product is verified by chemical analysis. In the United States, Suva® 407C and Suva®410A are included in the DuPont refrigerant reclama-tion program. Contact DuPont or one of its authorized distributors for further information.
¡¡Reclamation offers advantages over on-site refrigerant recycling procedures, because these systems cannot guarantee complete removal of contaminants. Putting refrigerants that do not meet new product specifica-tions back into expensive equipment may cause damage.

Recycle
¡¡Refrigerant recycle refers to the reduction of used refrigerant contaminants using devices that reduce oil, water, acidity, and particulates. Recycle is usually a field or shop procedure with no analytical testing of refrigerant. Before using one of these devices with Suva® 407C or Suva® 410A, consult the manufacturer to confirm compatibility.

Disposal
¡¡Disposal refers to the destruction of used Suva® 407C or Suva® 410A. Disposal may be necessary when Suva® 407C or Suva® 410A has become badly con-taminated with other products and no longer meets the acceptance specifications of DuPont or other reclaimers. Licensed waste disposal firms are avail-able for this purpose. Be sure to check the qualifica-tions of any firm before sending them used Suva®407C or Suva® 410A.



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